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I'm modeling this AWD system off of Audi's Quattro AWD system
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larger longitudinal engine Audis
As long as you remember that the quattro (Always with a little q) was and is the longer, longitudinal layout.
The engine, mounted to the front of a transaxle, with half shafts coming out of the transaxle driving the front wheels, and a output shaft coming out of the rear of the transaxle driving a rear differential.
The output shaft that comes out of the rear differential is drivinig at final gear speed (transmission) not final drive speed.
That means that the output going to the rear differential, is the same speed as what the front differential is seeing.
With the layout that you are using, turning a 020 trans 90 degs and the outputs from what would normally go to the front wheels you are now driving to the front and rear differentials.
One issue that I am seeing is one that you and I have already mentioned: finding a 1:1 differential that is capable of handling the load.
I think that you are right (at least I haven't found any data to presume otherwise) that the differential mounted in the rear of the syncro Passat, is a 1:1 differential.
Another problem is rotation direction.
If you mount the engine towards the front, the shafts will be turning clockwise (as seen by the rear differential). Which, if I remember correctly, is the wrong direction for the back end of the car, but will work just fine for the front end (using the Passat diffs).
Something else that was mentioned before was the load direction at the diffs, you were correct, the teeth in the diff are designed to be driven in only one direction. There is a drive side and a coast side. If you try to drive the coast side, you will probably blow up the diff case as the gears will try to push each other apart.